It was actually really difficult to get the point order, but you could check out this post below in the comment section.
Basically from the comments there is a link to blog post, in the blog post’s comments section you get an idea where the ordering, you’ll have to go through the C++ code for that at this link:
https://gitlab.kitware.com/nick.laurenson/vtk/blob/d8aa5b89c622cf04b3322112fda420afc9d2a16d/Common/DataModel/vtkLagrangeHexahedron.cxx
search for int vtkLagrangeHexahedron::PointIndexFromIJK(int i, int j, int k, const int* order)
Giving you a headsup, there are a few bugs in the viewer like below:
ParaView Support
Just out of curiosity may I know what you are working with or on?